Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [FeIII(acac2-trien)]+ and [FeIII(sal2-trien)]+ molecules
نویسندگان
چکیده
منابع مشابه
Graphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [FeIII(acac2-trien)]+ and [FeIII(sal2-trien)]+ molecules.
The syntheses, structures and magnetic properties of the coordination compounds of formula [FeIII(acac2-trien)][MnIICrIII(Cl2 An)3]·(CH3CN)2 (1), [FeIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (2) and [GaIII(acac2-trien)][MnIICrIII(Br2An)3]·(CH3CN)2 (3) are reported. They exhibit a 2D anionic network formed by Mn(ii) and Cr(iii) ions linked through anilate ligands, while the [FeIII(acac2-trie...
متن کاملGraphene related magnetic materials: micromechanical exfoliation of 2D layered magnets based on bimetallic anilate complexes with inserted [FeIII(acac2-trien)]+ and [FeIII(sal2-trien)]+ molecules† †Electronic supplementary information (ESI) available: Experimental section, structural views of 1, 2 and 3, powder X-ray diffraction patterns of 1, 2 and 3, isothermal magnetization of 1, 2 and 3 at 2 K, AC susceptibility measurements of 3, DLS, EDS analysis, optical microscopy, SEM, TEM and AFM images of flakes of 2 and 4. CCDC 1054372–1054374. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00957j Click here for additional data file. Click here for additional data file.
Instituto de Ciencia Molecular, Universidad Paterna, 46980, Spain. E-mail: miguel.cle Fax: +34 963543273; Tel: +34 963544405 † Electronic supplementary information structural views of 1, 2 and 3, powder X isothermal magnetization of 1, 2 and 3 a of 3, DLS, EDS analysis, optical micros akes of 2 and 4. CCDC 1054372–105437 CIF or other electronic format see DOI: 10 Cite this: Chem. Sci., 2015, 6...
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ژورنال
عنوان ژورنال: Chemical Science
سال: 2015
ISSN: 2041-6520,2041-6539
DOI: 10.1039/c5sc00957j